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Scientific American Supplement, No. 799, April 25, 1891
Author: Various
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It yields by distillation an oil termed "oil of spike," or, to distinguish it from oil of L. staechas, "true oil of spike." It is darker in color than the oil of L. vera, and much less grateful in odor, reminding one of turpentine and rancid coker nut oil. It is used by painters on porcelain, and in the manufacture of varnishes. It is often largely admixed with essence of turpentine.

L. Staechas (Stichas) was discovered prior to the year 50 A.D. in the Staechades Islands (now the Islands of Hyeres), hence the name. At present it is found wild in the South of Europe and North of Africa, also at Teneriffe. The leaves are oblong linear, about half an inch long (sometimes an inch long when cultivated), with revolute edges and clothed with hoary tomentum on both surfaces; the spike is tetragonal, compact, with a tuft of purple leaves at the top; the calyces are ovate and slightly shorter than the tube of the corolla. The whole plant has a strong aromatic and agreeable flavor. There is a variety of this species (L. macrostachya) native of Corsica, Sicily, and Naples, which has broader leaves and thicker octagonal spikes.

L. staechas is known in Spain as "Romero Santo" (sacred rosemary). Its essential oil (also that of L. dentata) is there obtained for household use by suspending the fresh flowering stalks, flowers downward, in closed bottles and exposing them for some time in the sun's rays; a mixture of water and essential oil collects at the bottom, which is used as a haemostatic and for cleansing wounds.

The specific gravity of Spanish oil of L. staechas is 0.942 at 15 deg. C. It boils between 180 deg. and 245 deg.. The odor of this oil is not at all suggestive of that of lavender, but resembles more that of oil of rosemary, possessing also the camphoraceous odor of that oil. In India this oil is much prized as an expectorant and antispasmodic.



The other species which are distinctly characterized are L. pedunculata, L. viridis, L. dentata, L. heterophylla, L. pyrenaica, L. pinnata, L. coronopifolia, L. abrotonoides, L. Lawii, and L. multifida.

The L. multifida is synonymous with L. Burmanii. In Spain the therapeutic properties of L. dentata are alleged to be even more marked than in the oils of any of the other species of lavender. It is said to promote the healing of sluggish wounds, and when used in the form of inhalation to have given good results in cases of severe catarrh, and even in cases of diphtheria. In odor this oil strongly suggests rosemary and camphor. Its specific gravity is 0.926 at 15 deg. C. It distills almost completely between 170 deg. and 200 deg..

The specific gravity of the oil of L. vera (according to Flueckiger and Hanbury, Pharmacographia) ranges between 0.87 and 0.94. The same authorities state that in a tube of 50 millimeters the plane of polarization is diverted 4.2 deg. to the left.

Dr. Gladstone found (Jnl. Ch. Soc., xviii., 3) that a sample of pure oil of L. vera, obtained from Dr. S. Piesse, indicated a specific gravity of 0.8903 at 15 deg. C., and that its power of rotating the plane of polarization (observed with a tube ten inches long) was -20 deg.. Compared with these results he found the sp. gr. of oil of turpentine to be 0.8727, and the rotatory power -79 deg..

Although L. staechas was well known to the ancients, no allusion unquestionably referring to L. vera has been found in the writings of classical authors, the earliest mention of this latter plant being in the twelfth century, by the Abbess Hildegard, who lived near Bergen-on-the-Rhine. Under the name of Llafant or Llafantly, it was known to the Welsh physicians as a medicinal plant in the thirteenth century. The best variety of L. vera—and there are several, although unnamed—improved by cultivation in England, presents the appearance of an evergreen undershrub of about two feet in height, with grayish green linear leaves, rolled under at the edges, when young; the branches are erect and give a bushy appearance to the plant; the flowers are borne on a terminal spike, at the summit of along naked stalk, the spike being composed of six to ten verticillasters, more widely separated toward the base of the spike; in young plants two or four sub-spikes will branch alternately in pairs from the main stalk; this indicates great vigor in the plant, and occurs rarely after the second year of the plant's growth. The floral leaves are rhomboidal, acuminate, and membraneous, the upper ones being shorter than the calyces, bracteas obovate; the calyces are bluish, nearly cylindrical, contracted toward the mouth, and ribbed with many veins. The corolla is of a pale bluish violet, of a deeper tint on the inner surface than the outer, tubular, two-lipped, the upper lip with two and the lower with three lobes. Both the corolla and calyx are covered with stellate hairs, among which are embedded shining oil glands, to which the fragrance of the plant is due. The L. vera was identified in 1541, and introduced into England in 1568, flourishing remarkably well under cultivation, and yielding an oil far superior in delicacy of fragrance to that obtained from the wild plant, or to that obtained from the same plant cultivated in any other country.

When it is remembered that north of the 50th degree of latitude the vine yields little but garlands of leaves, and that we should attempt in vain to cultivate the olive north of the 44th degree, it may seem strange that the Lavandula vera, which is a native of about the same climate as these, should resist, unprotected, the vigorous frosts of this country. Even at Upsala, latitude 59 deg. 51' N., in the Botanic Garden, it merely requires the shelter of a few branches to protect it in the winter; but this hardiness may be accounted for by several physiological reasons. Like all fruticulose labiates which have a hard compact tissue and contain much oily matter, the lavender absorbs less moisture than herbs which are soft and spongy, and, as it always prefers a dry calcareous, even stony, soil, the northern cultivators find that by selecting such localities the tissues of the plant take up so little water that the frost does not injure them.

In a northern climate the length of the days in summer, and the natural dryness of the air, compensate in some measure the reduction of temperature, and mature the plant only to the extent sufficient for the purpose for which it is grown. Perhaps the suspension of vital action during winter, which must be more complete in northern latitudes, as our frosts are more severe, tends to preserve certain plants, native of the south, for it is observed that all plants are more sensitive to cold when vegetation is active than when it is at rest. The vine is an instance of this. On the other hand, when the plant is cultivated further south than its natural boundary, the same causes seem to exert their influence, but in the reverse sense. Lavender is cultivated on the mountains of Yemen, in Arabia; the humidity, increasing inversely to the latitude, compensates the exhaling force of the sun's rays, and the elevation of the locality the effects of the heat.

Thus is confirmed, both in north and south, the law of vegetable physiology observed by De Candolle, in the temperate climates of France, and published in his "Essai de Geographie Botanique," that "plants can best resist the effects of cold in a dry atmosphere, and the effects of heat in a humid atmosphere." A mild, damp winter, like the one of 1889-1890, does more harm than a hard, seasonable frost, as the plants are apt to make green shoots prematurely, and the late frosts nip off these tender portions, each of which would otherwise have produced a flower spike.

The very severe winter of 1890-1891 did not kill so many plants as the one of 1889-1890. The stems and branches of lavender being ligneous and strong are able to resist the force of the wind, and the plant thrives best in a perfectly open locality, where the air circulates freely; the oil and resin which it contains in abundance enable it to resist the parching action of the wind and sun. Thus, on the most arid and sterile ground on the mountain sides in the south, and especially in Spain, plants of this genus flourish with more vigor in the season when most other vegetation is scorched up by the ardent rays of the sun, and the Lavandula vera seems to have a predilection for such spots.

Certainly the plants then assume a more stunted appearance than in richer soil, but at the same time the perfume is stronger and sweeter. The calyces become charged with oil glands, and yield a greater abundance of volatile oil.

In a very moist soil the water penetrates too much into the tissues, detaches the bark, the plant blackens at the root, and a white fungus attaches to the main stem and lower branches; it becomes feeble, diseased, and dies. A rich soil furnishes too much nutriment, the plant grows very large and herbaceous, becomes overcharged with water relative to its assimilating and elaboratory power, especially if growing in a cold climate, and the equilibrium of the chemical proportions necessary for the formation of natural juices becomes deranged at the expense of quantity and quality of the volatile oil produced.

These facts, long ago pointed out by Linnaeus, have been verified in England. Some years ago a disease manifested itself in most of the plantations, which, not being understood by the growers, was not remedied (in fact, is not generally understood and remedied at the present time), the acreage under cultivation decreased, and, partly owing to this and a scarcity occasioned by a failure in the crop, the price of the oil rapidly rose from 50s. to 200s. per lb. Consequently, with the continually increasing demand and the continued rise in price, manufacturers of lavender water and of compound perfumes in which oil of lavender is a necessary ingredient commenced to buy the French oil, and venders of the English oil commenced to adulterate largely the English with the French oil.

By degrees the French oil become almost entirely substituted in England for the English, and at present it is difficult to purchase true English lavender water of a quality equal to that vended twenty years ago, except at a few first class houses.

The exorbitant profits demanded by chemists and druggists, and the incomprehensible will of the public to buy anything cheap, however bad, have encouraged a marvelous increase in the figures of the imports of French (and German, which is worse) oil.

In 1880, when the price had reached 125s. per lb., it was pointed out by an eminent London firm that unless the cultivation in England were extended, the price would become prohibitive, inferior oils would be introduced into the market, and so destroy the popularity of this beautiful perfume.

The price still rising did, in fact, induce this importation, and to this day the bulk of chemists and perfumers continue to use these foreign oils, notwithstanding the fall in the price of the English oil.

The constant demand, however, in America (where people will have things good) will yet support the price of the genuine article—that is, of the English oil, which is the finest the world produces. Attempts were made by a French manufacturing perfumer to establish a plantation in the south of France of plants taken from parent stems grown in England.

The result was that the young plants deteriorated to their original condition—even there in their native habitat. The character of a plant and the character of its produce depend even on more than a similarity of soil and geographical position. It is asserted that a good judge can distinguish between the oils produced by two adjacent fields, and the difference in odor is very apparent between the oils produced in Hertfordshire and in Surrey. The oil produced in Sussex is different from both.—Chemist and Druggist.

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SPECTRUM OF THE SUN AND ELEMENTS.

The Johns Hopkins University Circular, No. 85, issued in February, contains Prof. Rowland's report of progress in spectrum work. The spectra of all known elements, with the exception of a few gaseous ones, or those too rare to be yet obtained, have been photographed in connection with the solar spectrum, from the extreme ultra-violet down to the D line, and eye observations have been made on many to the limit of the solar spectrum. A table of standard wave lengths of the impurities in the carbon poles extending to wave length 2,000 has been constructed to measure wave lengths beyond the limits of the solar spectrum. In addition to this, maps of the spectra of some of the elements have been drawn up on a large scale, ready for publication, and the greater part of the lines in the map of the solar spectrum have been identified. The following rough table of the solar elements has been constructed entirely according to Prof. Rowland's own observations, although, of course, most of them have been given by others:

Elements in the Sun, arranged according to Intensity and the Number of Lines in the Solar Spectrum.

According to intensity. According to number.

Calcium Zirconium Iron (2,000 or more) Magnesium (20 or more) Iron Molybdenum Nickel Sodium (11) Hydrogen Lanthanum Titanium Silicon Sodium Niobium Manganese Strontium Nickel Palladium Chromium Barium Magnesium Neodymium Cobalt Aluminum (4) Cobalt Copper Carbon (200 or more) Cadmium Silicon Zinc Vanadium Rhodium Aluminum Cadmium Zirconium Erbium Titanium Cerium Cerium Zinc Chromium Glucinum Calcium (75 or more) Copper (2) Manganese Germanium Scandium Silver (2) Strontium Rhodium Neodymium Glucinum (2) Vanadium Silver Lanthanum Germanium Barium Tin Yttrium Tin Carbon Lead Niobium Lead (1) Scandium Erbium Molybdenum Potassium (1) Yttrium Potassium Palladium

Doubtful Elements.

Iridium, osmium, platinum, ruthenium, tantalum, thorium, tungsten, uranium.

Not in Solar Spectrum.

Antimony, arsenic, bismuth, boron, nitrogen, caesium, gold, indium, mercury, phosphorus, rubidium, selenium, sulphur, thallium, praseodymium.

With respect to these tables, Prof. Rowland adds: "The substances under the head of 'Not in the Solar Spectrum' are often placed there because the elements have few strong lines or none at all in the limit of the solar spectrum when the arc spectrum, which I have used, is employed. Thus, boron has only two strong lines at 2497. Again, the lines of bismuth are all compound, and so too diffuse to appear in the solar spectrum. Indeed, some good reason generally appears for their absence from the solar spectrum. Of course, there is but little evidence of their absence from the sun itself; were the whole earth heated to the temperature of the sun, its spectrum would probably resemble that of the sun very closely."

The powerful instrument used at Baltimore for photographing spectra, and the measuring engine constructed to fit the photographs so that its readings give the wave lengths of lines directly within 1/100 of a division on Angstroem's scale, give the foregoing results a weight superior to many others published.

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ALLOTROPIC FORMS OF METALS.

Writing on some curious properties of metals and alloys, Mr. W.C. Roberts-Austen, says the Engineer, remarks that the importance of the isomeric and allotropic states has been much neglected in the case of metals. Joule and Lyon Playfair showed, in 1846, that metals in different allotropic states possess different atomic volumes, and Matthiessen, in 1860, was led to the view that in certain cases where metals are alloyed they pass into allotropic states, probably the most important generalization which has yet been made in connection with the molecular constitution of alloys. Instances of allotropy in pure metals are: Bolley's lead, which oxidizes readily in air; Schutzenberger's copper; Fritsche' tin, which falls to powder when exposed to exceptionally cold winter; Gore's antimony; Graham's palladium and allotropic nickel. Joule has also proved that, when iron is released from its amalgam by distilling away the mercury, the metallic iron takes fire on exposure to air, and is therefore clearly different from ordinary iron.

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